Reaction with Aldehydes Ketones

Primary amines react with aldehydes and ketone both aliphatic as well as aromatic in the presence of trace of acid to form azomethines called Schiff’s bases.



Schiff’s bases on reduction give secondary amines.


 

Secondary amines also react with aldehydes and ketones having H-atoms in the presence of a trace of acid, p-toluenesulphonic acid (PTS) to form enamine

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